This will do it.
if OBJECT_ID('tempdb..#Something') is not null
drop table #Something
create table #Something
(
SomeID int identity,
SomeValue varchar(25)
)
insert #Something
select '1,2,3,4,5' union all
select '6,7,8,9,10'
select MAX(Case when ItemNumber = 1 then Item else null end) as ColA,
MAX(Case when ItemNumber = 2 then Item else null end) as ColB,
MAX(Case when ItemNumber = 3 then Item else null end) as ColC,
MAX(Case when ItemNumber = 4 then Item else null end) as ColD,
MAX(Case when ItemNumber = 5 then Item else null end) as ColE
from #Something s
cross apply dbo.DelimitedSplit8K(s.SomeValue, ',') x
group by SomeID
You can find the code for the DelimitedSplit8K function by following the article in my signature about splitting strings.
Notice how I posted ddl and sample data? You should do something like that in the future.
Then when you parse this stuff out you should store your data normalized. Storing multiple values in a single column violates first normal form.
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Need to split a string? Try Jeff Modens splitter http://www.sqlservercentral.com/articles/Tally+Table/72993/.
Cross Tabs and Pivots, Part 1 – Converting Rows to Columns - http://www.sqlservercentral.com/articles/T-SQL/63681/
Cross Tabs and Pivots, Part 2 - Dynamic Cross Tabs - http://www.sqlservercentral.com/articles/Crosstab/65048/
Understanding and Using APPLY (Part 1) - http://www.sqlservercentral.com/articles/APPLY/69953/
Understanding and Using APPLY (Part 2) - http://www.sqlservercentral.com/articles/APPLY/69954/