• Tried all of the following:

    ProdB

    ProdB,1433

    ProdB.my.dom

    ProdB.my.dom,1433

    AliasToProdB

    AliasToProdB,1433

    AliasToProdB.my.dom

    AliasToProdB.my.dom,1433

    Nothing works. Keep in mind, as I stated in my OP, all this works fine if I am logged into the DevC server (RDS or physically), which confirms to me that the target servers are configured identically. And, since users are not allowed to log in to servers, and they will be running queries from their desktops (via SSMS), it needs to work that way.