Hi and welcome to the forums. The best chance you have of people helping is if you first post ddl and sample data in a consumable format. Most people won't even bother with your post if you post an excel doc. I took the risk this time. I have formatted your data into something consumable to demonstrate what I mean.
if object_id('tempdb..#PayData') is not null
drop table #PayData
create table #PayData
(
Dept int,
DeptDesc varchar(5),
PayDate datetime,
Pay numeric(7,2)
)
insert #PayData
select 006051, 'CNA', '2013-01-04', 18.53 union all
select 006051, 'CNA', '2013-01-04', 19.16 union all
select 003000, 'RN', '2013-01-04', 3.86 union all
select 003100, 'LPN', '2013-01-04', 11.54 union all
select 006051, 'CNA', '2013-01-04', 3.76 union all
select 005410, 'RN', '2013-01-04', 16.44 union all
select 003100, 'RN', '2013-01-04', 6.08 union all
select 005410, 'RN', '2013-01-04', 12.81 union all
select 805410, 'RN', '2013-01-04', 12.35 union all
select 006051, 'CNA', '2013-01-04', 15.02 union all
select 003000, 'LPN', '2013-01-04', 2.25 union all
select 003100, 'LPN', '2013-01-04', 10.03 union all
select 006051, 'CNA', '2013-01-04', 10.33 union all
select 006051, 'CNA', '2013-01-04', 3.51 union all
select 003000, 'RN', '2013-01-04', 11.91 union all
select 006050, 'LPN', '2013-01-04', 3.53 union all
select 806050, 'RN', '2013-01-04', 12.81 union all
select 006031, 'R.N.', '2013-01-04', 49.86 union all
select 006020, 'LPN', '2013-01-04', 5.67
Now I think that this query will produce the results you are looking for but from the brief description it is hard to say for sure.
select * from
(
select case when DeptDesc in ('LPN', 'RN', 'R.N.') then 'Nurse' else DeptDesc end as DeptDesc,
sum(Pay) over(partition by case when DeptDesc in ('LPN', 'RN', 'R.N.') then 'Nurse' else DeptDesc end ) as TotalPay
from #PayData
group by case when DeptDesc in ('LPN', 'RN', 'R.N.') then 'Nurse' else DeptDesc end, Pay
)x
group by DeptDesc, TotalPay
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