besides identifying the columns in the table, you need another attribute to identify what makes a collection of columns unique, especially if it's not the PK of the table and there's no unique constraint.;
for example,
<fieldMapping DefaultField="Lastname" databaseField="Surname" IsPartOfUniqueCriteria="true">
then your app can use Linq or whatever to group the data by the IsPartOfUniqueCriteria=true columns and look for duplicates;
Lowell