You can also use the below : Here it lists all Orphaned users on existing DB and delete Ids and associated Schema .
DECLARE @UserName varchar(100),
@SQL as varchar(max)
create table ##orphans (orphan varchar(128))
-- 1)
if substring(@@version, 1, 26) not in ('Microsoft SQL Server 2000', 'Microsoft SQL Server 2000')
insert into ##orphans select u.name as 'Orphaned Users' from sys.server_principals l right join sys.database_principals u on
l.sid = u.sid where l.sid is null and u.type not in ('A','R') and (u.name <> 'INFORMATION_SCHEMA' and u.name <> 'guest' and
u.name <> 'system_function_schema' and u.name <> 'sys' and not db_name() + '.' + u.name= 'msdb.MS_DataCollectorInternalUser')
else
select u.name as 'Orphaned Users' from master..sysxlogins l right join sysusers u on l.sid = u.sid where l.sid is null and
issqlrole <> 1 and isapprole <> 1 and (u.name <> 'INFORMATION_SCHEMA' and u.name <> 'guest' and u.name <> 'system_function_schema')
DECLARE mycurs CURSOR FOR
SELECT
orphan
FROM
##orphans
OPEN mycurs
FETCH NEXT FROM mycurs
INTO @username
WHILE @@FETCH_STATUS = 0
BEGIN
-- 2)
BEGIN TRY
EXEC sp_change_users_login @Action='update_one', @UserNamePattern=@UserName, @LoginName=@UserName
END TRY
BEGIN CATCH
print @Username + ' does not exist as a Login. Deleting. '
-- 3)
BEGIN TRY
SET @SQL = 'DROP SCHEMA [' + @UserName +']'
EXEC (@SQL)
END TRY
BEGIN CATCH
END CATCH
-- 4)
SET @SQL = 'DROP USER [' + @UserName + ']'
Print @SQL
EXEC (@SQL)
END CATCH
FETCH NEXT FROM mycurs
INTO @username
END
CLOSE mycurs
DEALLOCATE mycurs
DROP TABLE ##orphans