Just use CROSS APPLY to introduce the expression, and then you can just give it a name you can reference.
Here's a quick example illustrating it:
SELECT object_id,
case_result,
--can be referenced by name now
derived_from_case='Simple concat: '+case_result
--can also be referenced by name in other operations
FROM sys.objects O
CROSS APPLY
(SELECT CASE
WHEN O.object_id<100 THEN 'Less than 100'
WHEN O.object_id>=100 THEN 'Greater than or equal to 100'
END
)cross_applied(case_result)
In 2008 on, you could also CROSS APPLY VALUES instead of doing the SELECT.
Cheers!