One thing to make sure is to not schedule multiple subscriptions for the same report to run all at the same time. This could cause a series of issues including deadlocking.

If that is not your issue you can reference SQL Job history on the SSRS server / Event Viewer. Just match up your subscription run times.

Lastly you can check the SSRS log files on the SSRS server:

C:\Program Files\Microsoft SQL Server\MSRS10.MSSQLSERVER\Reporting Services\LogFiles