suresh,
Try this: -
select OrderFormNo
,ClientName
,OrderDate
,Product
,sum(Value)
,InvoiceQuantity
,PendingQuantity
from AOM_Tbl_PendingOrders
group by OrderFormNo, ClientName,OrderDate,Product,InvoiceQuantity,PendingQuantity
In your case, remember that whenever you use the group by clause you need to add all the other colums as well except the function column (i.e. sum)