These links should get you started
http://www.microsoft.com/learning/mcp/mcts/sql/default.mspx
http://www.microsoft.com/learning/mcp/mcitp/dbdev/default.mspx
http://www.microsoft.com/learning/mcp/mcitp/dbadmin/default.mspx
Gail Shaw
Microsoft Certified Master: SQL Server, MVP, M.Sc (Comp Sci)
SQL In The Wild: Discussions on DB performance with occasional diversions into recoverability