You can use CmdExec method (Using operating system command) also to run the command.
To Use the extended stored procedure xp_cmdShell, it needs to be enabled. By default it is disabled due to security concerns.
The Job Step will be some thing like this:
EXEC @ReturnCode = msdb.dbo.sp_add_jobstep @job_id=@jobId, @step_name=N'copy file',
@step_id=1,
@cmdexec_success_code=0,
@on_success_action=1,
@on_success_step_id=0,
@on_fail_action=2,
@on_fail_step_id=0,
@retry_attempts=0,
@retry_interval=0,
@os_run_priority=0,
@subsystem=N'CmdExec',
@command=N'ccopy c:\myfolder\myfile.txt d:\yourfolder\yourfile.txt',
@flags=0
Cheers,
Prithiviraj Kulasingham
http://preethiviraj.blogspot.com/