I found this in the log.
Date3/8/2013 8:16:52 AM
LogWindows NT (Red Gate Software)
SourceSQL Doc 2
Category(0)
Event32
ComputerMYPC
Message
CommandLine
Main:Unhandled Exception
System.ArgumentNullException: Value cannot be null.
Parameter name: value
at System.IO.Directory.SetCurrentDirectory(String path)
at System.Environment.set_CurrentDirectory(String value)
at RedGate.SQLDoc.Engine.Project.Project.(String )
at RedGate.SQLDoc.Engine.Project.Project.set_FilePathOfHtml(String value)
at RedGate.SQLDoc.Engine.Project.Project..ctor()
at RedGate.SQLDoc.Engine.Project.Project.LoadFromDisk(String pathAndFileName)
at RedGate.SQLDoc.UI.CommandProcessor.RunProject()
at RedGate.SQLDoc.UI.CommandProcessor.Run()
at RedGate.SQLDoc.UI.Program.Main(String[] args)