You get the below error on the second backup
Msg 3023, Level 16, State 2, Line 1
Backup, file manipulation operations (such as ALTER DATABASE ADD FILE) and encryption changes on a database must be serialized. Reissue the statement after the current backup or file manipulation operation is completed.
Msg 3204, Level 16, State 1, Line 1
The backup or restore was aborted.
Msg 3013, Level 16, State 1, Line 1
BACKUP DATABASE is terminating abnormally.