You should probably use pivot operation (I hope somebody will post an example), but this should also work:
use tempdb
declare @t table (
Skill varchar(10) not null,
BU1 int not null,
BU2 int not null,
Bu3 int not null
)
insert into @t
values
('Skill1', 0, 0, 0),
('Skill2', 2, 6, 0),
('Skill3', 0, 0, 7),
('Skill4', 4, 0, 0),
('Skill5', 0, 7, 8)
;with temp as (
select 'BU1' BU, Skill, BU1 Value from @t union all
select 'BU2' BU, Skill, BU2 Value from @t union all
select 'BU3' BU, Skill, BU3 Value from @t
)
select *
from temp
order by BU, Skill