I'm going to guess that the problem is your XML.

Let's take a look at the XML formatted to be readable: -

<Root>

<Node FirstName="Andrew" LastName="Fuller" Email="afuller@contoso.com" Phone="(205) 555 - 9898" Position="CEO" Branch="TopManagement" Address="London, 120 Hanover Sq.">

<Node FirstName="Jeremy" LastName="Boather" Email="jboather@contoso.com" Phone="(205) 555 - 9888" Position="President QA" Branch="QA" Address="London, 120 Hanover Sq.">

<Node FirstName="Anne" LastName="Dodsworth" Email="adodsworth@contoso.com" Phone="(205) 555 - 9887" Position="VP QA" Branch="QA" Address="London, 120 Hanover Sq.">

<Node FirstName="Alexander" LastName="Tuckings" Email="atuckings@contoso.com" Phone="(205) 555 - 9886" Position="Team Lead Team1" Branch="QA" Address="London, 120 Hanover Sq.">

<Node FirstName="Brenda" LastName="Smith" Email="bsmith@contoso.com" Phone="(205) 555 - 9885" Position="Senior QA" Branch="QA" Address="London, 120 Hanover Sq." />

</Node>

<Node FirstName="Mary" LastName="Bird" Email="mbird@contoso.com" Phone="(205) 555 - 9885" Position="Team Lead Team2" Branch="QA" Address="London, 120 Hanover Sq." />

</Node>

</Node>

<Node FirstName="Steven" LastName="Buchanan" Email="sbuchanan@contoso.com" Phone="(205) 555 - 9897" Position="President Dev Dept." Branch="Development" Address="London, 120 Hanover Sq.">

<Node FirstName="Robert" LastName="King" Email="rking@contoso.com" Phone="(205) 555 - 9896" Position="VP Dev Dept." Branch="Development" Address="London, 120 Hanover Sq.">

<Node FirstName="Laura" LastName="Callahan" Email="lcallahan@contoso.com" Phone="(205) 555 - 9892" Position="Team Lead Team1" Branch="Development" Address="London, 120 Hanover Sq.">

<Node FirstName="Jason" LastName="Roland" Email="jroland@contoso.com" Phone="(205) 555 - 9872" Position="Senior Dev" Branch="Development" Address="London, 120 Hanover Sq." />

</Node>

<Node FirstName="Eric" LastName="Danstin" Email="edanstin@contoso.com" Phone="(205) 555 - 9882" Position="Team Lead Team2" Branch="Development" Address="London, 120 Hanover Sq.">

<Node FirstName="Elizabeth" LastName="Lincoln" Email="elincoln@contoso.com" Phone="(205) 555 - 9862" Position="Senior Dev" Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Margaret" LastName="Peacock" Email="mpeacock@contoso.com" Phone="(205) 555 - 9852" Position="Senior Dev" Branch="Development" Address="London, 120 Hanover Sq." />

</Node>

</Node>

</Node>

</Node>

</Root>

So, I'm guessing that what your XML is supposed to look like is this: -

<Root>

<Node FirstName="Andrew" LastName="Fuller" Email="afuller@contoso.com" Phone="(205) 555 - 9898" Position="CEO" Branch="TopManagement" Address="London, 120 Hanover Sq." />

<Node FirstName="Jeremy" LastName="Boather" Email="jboather@contoso.com" Phone="(205) 555 - 9888" Position="President QA" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Anne" LastName="Dodsworth" Email="adodsworth@contoso.com" Phone="(205) 555 - 9887" Position="VP QA" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Alexander" LastName="Tuckings" Email="atuckings@contoso.com" Phone="(205) 555 - 9886" Position="Team Lead Team1" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Brenda" LastName="Smith" Email="bsmith@contoso.com" Phone="(205) 555 - 9885" Position="Senior QA" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Mary" LastName="Bird" Email="mbird@contoso.com" Phone="(205) 555 - 9885" Position="Team Lead Team2" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Steven" LastName="Buchanan" Email="sbuchanan@contoso.com" Phone="(205) 555 - 9897" Position="President Dev Dept." Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Robert" LastName="King" Email="rking@contoso.com" Phone="(205) 555 - 9896" Position="VP Dev Dept." Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Laura" LastName="Callahan" Email="lcallahan@contoso.com" Phone="(205) 555 - 9892" Position="Team Lead Team1" Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Jason" LastName="Roland" Email="jroland@contoso.com" Phone="(205) 555 - 9872" Position="Senior Dev" Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Eric" LastName="Danstin" Email="edanstin@contoso.com" Phone="(205) 555 - 9882" Position="Team Lead Team2" Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Elizabeth" LastName="Lincoln" Email="elincoln@contoso.com" Phone="(205) 555 - 9862" Position="Senior Dev" Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Margaret" LastName="Peacock" Email="mpeacock@contoso.com" Phone="(205) 555 - 9852" Position="Senior Dev" Branch="Development" Address="London, 120 Hanover Sq." />

</Root>

Now, if we execute your code against the corrected XML: -

DECLARE @idoc INT;

DECLARE @doc XML;

SET @doc =

'<Root>

<Node FirstName="Andrew" LastName="Fuller" Email="afuller@contoso.com" Phone="(205) 555 - 9898" Position="CEO" Branch="TopManagement" Address="London, 120 Hanover Sq." />

<Node FirstName="Jeremy" LastName="Boather" Email="jboather@contoso.com" Phone="(205) 555 - 9888" Position="President QA" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Anne" LastName="Dodsworth" Email="adodsworth@contoso.com" Phone="(205) 555 - 9887" Position="VP QA" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Alexander" LastName="Tuckings" Email="atuckings@contoso.com" Phone="(205) 555 - 9886" Position="Team Lead Team1" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Brenda" LastName="Smith" Email="bsmith@contoso.com" Phone="(205) 555 - 9885" Position="Senior QA" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Mary" LastName="Bird" Email="mbird@contoso.com" Phone="(205) 555 - 9885" Position="Team Lead Team2" Branch="QA" Address="London, 120 Hanover Sq." />

<Node FirstName="Steven" LastName="Buchanan" Email="sbuchanan@contoso.com" Phone="(205) 555 - 9897" Position="President Dev Dept." Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Robert" LastName="King" Email="rking@contoso.com" Phone="(205) 555 - 9896" Position="VP Dev Dept." Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Laura" LastName="Callahan" Email="lcallahan@contoso.com" Phone="(205) 555 - 9892" Position="Team Lead Team1" Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Jason" LastName="Roland" Email="jroland@contoso.com" Phone="(205) 555 - 9872" Position="Senior Dev" Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Eric" LastName="Danstin" Email="edanstin@contoso.com" Phone="(205) 555 - 9882" Position="Team Lead Team2" Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Elizabeth" LastName="Lincoln" Email="elincoln@contoso.com" Phone="(205) 555 - 9862" Position="Senior Dev" Branch="Development" Address="London, 120 Hanover Sq." />

<Node FirstName="Margaret" LastName="Peacock" Email="mpeacock@contoso.com" Phone="(205) 555 - 9852" Position="Senior Dev" Branch="Development" Address="London, 120 Hanover Sq." />

</Root>';

EXEC sp_xml_preparedocument @idoc OUTPUT, @doc;

SELECT *

FROM OPENXML(@idoc, '/Root/Node', 1)

WITH (FirstName VARCHAR(110), LastName VARCHAR(210), Email VARCHAR(110), Phone VARCHAR(110), Position VARCHAR(110), Branch VARCHAR(110), Address VARCHAR(110)

);

The results returned are: -

FirstName LastName Email Phone Position Branch Address

---------- ---------- ---------------------- ------------------ -------------------- --------------- -------------------------

Andrew Fuller afuller@contoso.com (205) 555 - 9898 CEO TopManagement London, 120 Hanover Sq.

Jeremy Boather jboather@contoso.com (205) 555 - 9888 President QA QA London, 120 Hanover Sq.

Anne Dodsworth adodsworth@contoso.com (205) 555 - 9887 VP QA QA London, 120 Hanover Sq.

Alexander Tuckings atuckings@contoso.com (205) 555 - 9886 Team Lead Team1 QA London, 120 Hanover Sq.

Brenda Smith bsmith@contoso.com (205) 555 - 9885 Senior QA QA London, 120 Hanover Sq.

Mary Bird mbird@contoso.com (205) 555 - 9885 Team Lead Team2 QA London, 120 Hanover Sq.

Steven Buchanan sbuchanan@contoso.com (205) 555 - 9897 President Dev Dept. Development London, 120 Hanover Sq.

Robert King rking@contoso.com (205) 555 - 9896 VP Dev Dept. Development London, 120 Hanover Sq.

Laura Callahan lcallahan@contoso.com (205) 555 - 9892 Team Lead Team1 Development London, 120 Hanover Sq.

Jason Roland jroland@contoso.com (205) 555 - 9872 Senior Dev Development London, 120 Hanover Sq.

Eric Danstin edanstin@contoso.com (205) 555 - 9882 Team Lead Team2 Development London, 120 Hanover Sq.

Elizabeth Lincoln elincoln@contoso.com (205) 555 - 9862 Senior Dev Development London, 120 Hanover Sq.

Margaret Peacock mpeacock@contoso.com (205) 555 - 9852 Senior Dev Development London, 120 Hanover Sq.

Is that more in line with what you were after?