Olaf,
I got it to work, sort of. (Well, in my bar graph.)
I created a simple bar graph with (Date, Value), so the x-axis represents dates. If you right-click on a bar in the graph, you can change the color rule. Go to Series Properties, and Fill. Then enter an expression like this one:
=IIF(Weekday(Fields!TheDate.Value)>=6,"Red","Automatic")
{6=Saturday, 7=Sunday}
Hope this helps,
Pieter